I always use Golden Olive as an e/s - almost always with Green (frost) piggie which was sadly DC. But I often wear it with Gold Dusk, Emerald Green, Melon, Rose, any of the purples are also nice. Honestly it goes with everything, including the taupes and browns, I havent seen an awful Golden Olive combo yet. It also makes a HOT mascara if you tint some clear mascara with it!! Melon is much the same - its such a universal colour you can use it for anything. I especially like Melon as a blush - just use a big soft brush and apply gently, or as lip colour - tinted lipgloss is the nicest.
Sunset looks - there are soooooo many colours to choose from its impossible to list them all. Heres a couple of piggies that might help - Accent Red, Ruby Red, Revved Up, Apricot Pink, Pink Bronze, Off The Radar, Gold Dusk, Golden Lemon, Gold frost, Melon, Goldenaire, Deckchair, Jardin Aires, Dazzleray and Gold Mode