I find that Superdrug habour some amazing, almost undiscovered brands.
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Barry.M I would say have the best loose shadows and a fantastic range that have great pigmentation, although some of them do stain and they're like a fiver for a small pot.
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MUA are a incredible, they sell shadows for a mere pound per product and they are highly pigmented and creamy
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GOSH have amazing Quads and Trios...now I swatched these and they lasted on my hand, without a base most of the day, however the blue shade that I did swatch did stain my hand- then again, I'm pale, so it might not do that for you.
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Collection 2000 have amazing loose shadows aka pigments, which I say, some are a dupe for MAC however, my superdrug store don't really possess much of a colour range.. here is a swatch of that....